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Publications

Present-2010

Y. Lin, J. Genzer, W., Li, R. Qiao, M.D. Dickey, S.-Y. Tang, “Sonication-enabled Rapid Production of Stable Liquid Metal Nanoparticles Grafted with Poly(1-octadecene-alt-maleic anhydride) in Aqueous Solutions”, Nanoscale, in press (2018).

J. Jelken, P. Chinnayan Kannan, J. Genzer, N. Lomadze, S. Santer, “Fabrication of flexible hydrogel sheets featuring periodically spaced circular holes with continuously adjustable size in real time”, ACS Applied Materials & Interfaces 10, 30844-30851 (2018).

A.M. Hubbard, D.S. Davis, M.D. Dickey, J. Genzer, “Shape Memory Polymers for Self-Folding via Compression of Thermoplastic Sheets”, Journal of Applied Polymer Science 135, 46889 2018.

Y. Li, Y. Lin, Y. Ko, D. Kiserow, J. Genzer, “Visualization of Mechanochemically-Assisted Degrafting of Surface-Tethered Poly(Acrylic Acid) Brushes”, ACS Macro Letters 7, 609-613 (2018).

C.K. Pandiyarajan, J. Genzer, “Thermally activated one-pot, simultaneous radical and condensation reactions generate surface-anchored network layers from common polymers”, submitted (2018).

Y. Ko, J.R. Miles, J. Genzer, “Determining accurate dry thickness of hydrophilic polymer films”, submitted (2018).

S. Turgman-Cohen, J. Genzer, “Computer simulation of surface-initiated controlled radical polymerization: Effect of free-monomer model on brush properties”, submitted (2018).

R. Patil, J. Miles, Y. Ko, P. Datta, B. Rao, D. Kiserow, J. Genzer, “Kinetic study of degrafting mechanism of tetrabutyl ammonium fluoride on poly(methyl methacrylate) brushes”, submitted (2018).

C.B. Cooper, I. Joshipura, D. Parekh, J. Norkett, R. Mailen, V.M. Miller, J. Genzer, M.D. Dickey, “Tough Metamaterial Fibers for Energy Dissipation at Large Tensile Strains”, submitted (2018).

Y.K. Jhon, C.J. Galvin, B. Hammouda, R. Krishnamoorti, J. Genzer, “Phase behavior of random copolymers with tunable co-monomer sequences in solutions”, submitted (2018).

J. Bennett, A. Kristof, V. Vasudevan, J. Genzer, J. Srogl, M. Abolhasani, “Microfluidic Synthesis of Silicone Elastomer Microgels Using On-Chip Chemical Cross-Linking: A Case Study in Catalysis of Palladium-Mediated Cross-Coupling”, AIChe Journal 64, 3188-3197 (2018).

J.R. Miles, S.L. Schlenker, Y. Ko, R.R. Patil, B.M. Rao, J. Genzer, “Design and Fabrication of Wettability Gradients with Tunable Profiles Through Degrafting Organosilane Layers from Silica Surfaces by Tetrabutylammonium Fluoride”, Langmuir 33, 14556-14564 (2017).

P.K. Schoch, J. Genzer, “Adsorption of Size-Polydisperse Particles on Sinusoidally-Corrugated Surfaces”, Molecular Simulations 44, 494-506 (2017).

R.W. Mailen, M.D. Dickey, J. Genzer, M. Zikry, “Effects of Thermo-Mechanical Behavior and Hinge Geometry on Folding Response of Shape Memory Polymer Sheets”, Journal of Applied Physics 122, 195103 (2017).

S. Christau, T. Möller, J. Genzer, R. Köhler, R. von Klitzing, “Salt-induced aggregation of negatively charged gold nanoparticles confined in a polymer brush matrix”, Macromolecules 50, 7333-7343 (2017).

Y. Li, Y. Ko, Y. Lin, D. Kiserow, J. Genzer, “Enhanced Stability of Surface-tethered Diblock Copolymer Brushes with a Neutral Polymer Block and a Weak Polyelectrolyte Block: Effects of Molecular Weight and Hydrophobicity of the Neutral Block”, Macromolecules 50, 8580-8587 (2017).

Y. Lin, O. Gordon, M.R. Khan, N. Vasquez, J. Genzer, M.D. Dickey, “Vacuum Filling of Complex Microchannels with Liquid Metal”, Lab on Chip 17, 3043- 3050 (2017).

S. Applin, R.C. Schmitz; P.I. Tiemsin; J. Genzer; J.W Connell; C.J. Wohl, “Further Insight into the Mechanism of Poly(styrene-co-methyl methacrylate) Microsphere Formation”, Journal of Polymer Science, Polymer Chemistry 55, 2249-2259 (2017).

R.W. Mailen, M.D. Dickey, J. Genzer, M.A. Zikry, “A Fully-Coupled Thermo-Viscoelastic Finite Element Model for Self-Folding Shape Memory Polymer Sheets”, Journal of Polymer Science, Polymer Physics 55, 1207-1219 (2017).

Y. Lin, Y. Liu. J. Genzer, M.D. Dickey, “Turning Liquids into Solids by Heating: Shape-transformable Liquid Metal Nanoparticles in Aqueous Solution”, Chemical Science 8, 3832-3936 (2017).

C.B. Cooper, K. Arutselvan, Y. Liu, D. Armstrong, Y. Lin, M. Rashed Khan, J. Genzer, M.D. Dickey, “Stretchable Capacitive Sensors of Torsion, Strain, and Touch Using Double Helix Liquid Metal Fibers”, Advanced Functional Materials 1605630 (2017).

C.K. Panidyarajan, J. Genzer, “Effect of network density in surface-anchored poly(N-isopropylacrylamide) hydrogels on adsorption of fibrinogen”, Langmuir 33, 1974-1983 (2017).

A.M. Hubbard, R.W. Mailen, M.A. Zikry, M.D. Dickey, J. Genzer, “Controllable Curvature from Planar Polymer Sheets in Response to Light”, Soft Matter 13, 2299-2308 (2017).

C.B. Cooper, K. Arutselvan, Y. Liu, D. Armstrong, Y. Lin, M.R. Khan, J. Genzer, M.D. Dickey, “Stretchable Capacitive Sensors of Torsion, Strain, and Touch Using Double Helix Liquid Metal Fibers”, Advanced Functional Materials, 1605630 (2017).

Y. Liu, B. Shaw, M.D. Dickey, J. Genzer, “Sequential Self-folding of Polymer Sheets”, Science Advances 3, e1602417 (2017).

S. MacEwan, I. Weitzhandler, I. Hoffmann, J. Genzer, M. Gradzielski, A. Chilkoti, “Phase behavior and self-assembly of perfectly sequence-defined and monodisperse multi-block copolypeptides”, Biomacromolecules, 18, 599-609 (2017).

G.A. Castillo, L. Wilson, K. Efimenko, M.D. Dickey, C.B. Gorman, J. Genzer, “Amidation of polyesters is slow in nonaqueous solvents: Efficient amidation of poly(ethylene terephthalate) with 3-aminopropyltriethoxysilane in water for generating multifunctional surfaces”, ACS Appl. Mater. Interfaces 8, 35641−35649 (2016).

C. Cruz-Teran, K. Carlin, K. Efimenko, J. Genzer, B.M. Rao, “Targeted mutagenesis and combinatorial library screening enables control of protein orientation on surfaces and increased activity of adsorbed proteins”, Langmuir 32, 8660-9667 (2016).

A. Kopyshev, C.J. Galvin, R.R. Patil, J. Genzer, N. Lomadze, D. Feldmann, J. Zakrevski, S. Santer, “Light-induced reversible change of roughness and thickness of photosensitive polymer brushes”, ACS Applied Materials & Interfaces 8, 19175-19184 (2016).

C.K. Panidyarajan, M.R. Rubinstein, J. Genzer, “Surface-Anchored Poly(N‑isopropylacrylamide) Orthogonal Gradient networks”, Macromolecules 49, 5076-5083 (2016).

Y. Lin, C. Ladd, S. Wang, A. Martin, J. Genzer, S.A. Khan, M.D. Dickey, “Drawing Liquid Metal Wires at Room Temperature”, Extreme Mechanics Letters 7, 55-63(2016).

C.J. Galvin, J. Genzer, “Swelling of hydrophilic polymer brushes by water and alcohol vapors”, Macromolecules 49, 4316-4329 (2016).

S. Christau, T. Moeller, F. Brose, J. Genzer, O. Soltwedel, R. von Klitzing, “Effect of gold nanoparticle hydrophobicity on thermally induced color change of PNIPAM brush/gold nanoparticle hybrids”, Polymer 98, 454-463 (2016).

A. Kopyshev, C.J. Galvin, J. Genzer, N. Lomadze, D. Feldmann, S. Santer, “Polymer brushes modified by photosensitive azobenzene containing polyamines” Polymer 98, 421-428 (2016).

A.E. Özçam, K. Efimenko, R.J. Spontak, D.A. Fischer, J. Genzer, “Multipurpose Polymeric Coating for Functionalizing Inert Polymer Surfaces”, ACS Applied Materials & Interfaces 8, 5694-5705 (2016).

D. Davis, B. Chen, M.D. Dickey, J. Genzer, “Self-folding of Thick Polymer Sheets Using Gradients of Heat”, Journal of Mechanisms and Robotics 8, 0310141-1 -8 (2016).

F. Shen, O. Rojas, J. Genzer, P. Gurgel, R. Carbonell, "Affinity Interactions of Human Immunoglobulin G with Short Peptides: Role of Ligand Spacer on Binding, Kinetics and Mass Transfer," Analytical and Bioanalytical Chemistry, 408, 1829-1841 (2016).

Y. Liu, J. Genzer, M.D. Dickey, "’2D or Not 2D’: Shape-Programming Polymer Sheets," Progress of Polymer Sciences, 52, 79-106 (2016).

P. Datta, J. Genzer, "Modification of silicone elastomer surfaces with zwitterionic polymers: Short term fouling resistance and triggered biofouling release," ACS Applied Materials & Interfaces, 7, 25586-25591 (2015).

P. Datta, J. Genzer, "'Grafting through' polymerization involving surface-bound monomers," Journal of Polymer Science, Polymer Chemistry, 54, 263-274 (2015).

D. Davis, R. Mailen, J. Genzer, M.D. Dickey, "Self-folding of polymer sheets microwaves and graphene ink," RSC Advances, 5, 89254-89261 (2015).

R.R. Patil, D. Kiserow, J. Genzer, "Creating surface patterns of polymer brushes by degrafting via tetrabutyl ammonium fluoride," RSC Advances, 5, 86120-86125 (2015).

Y. Lin, C. Cooper, M. Wang, J. Adams, J. Genzer, M.D. Dickey, "Handwritten, Soft Circuit Boards and Antennas Using Liquid Metal Nanoparticles," Small, 11, 6397-6403 (2015).

A. Kopyshev, N. Lomadze, D. Feldmann, J. Genzer, S. Santer, "Making polymer brush photosensitive with azobenzene containing surfactants," Polymer, 79, 65-72 (2015).

R.W. Mailen, Y. Liu, M.D. Dickey, M. Zikry, J. Genzer, "Modelling of shape memory polymer sheets that self-fold in response to localized heating," Macromolecules, 48, 5677-5688 (2015).

C.J. Galvin, E.D. Bain, J. Genzer, "Instability of surface-grafted weak polyacid brushes on flat substrates," Macromolecules, 48, 5677-5688 (2015).

Z. Yenice, S. Schön, H. Bildirir, J. Genzer, R. von Klitzing, "Thermoresponsive PDMAEMA brushes: Effect of Gold Nanoparticle Deposition," Journal of Physical Chemistry B, 119, 10348-10358 (2015).

X.J. Cai, H.-M. Yuan, A. Benclowe, G.G. Qiao, J. Genzer, R.J. Spontak, "Film-Stabilizing Attributes of Polymeric Core-Shell Nanoparticles," ACS Nano, 9, 7940-7949 (2015).

H.A. Klok, J. Genzer, "Expanding the Polymer Mechanochemistry Toolbox through Surface-Initiated Polymerization," ACS Macro Letters, 4, 636-639 (2015).

Y. Liu, M.D. Casper, O. Gozen, S. Desai, E. Klem, J. Lewis, J-P. Maria, M.D. Dickey, J. Genzer, "Buckled topography to enhance light absorption in thin film organic photovoltaics," Zeitschrift für Physikalische Chemie, 7-8, 1251-1261 (2015).

S. Christau, J. Genzer, R. von Klitzing, "Polymer brush/metal nanoparticle hybrids for optical sensor applications: From self-assembly to tailored functions and nanoengineering," Zeitschrift für Physikalische Chemie, 7-8, 1089-1117 (2015).

R. Malik, J. Genzer, C.K. Hall, "Protein-like Copolymers as Encapsulating Agents for Small Molecule Solutes," Langmuir, 31, 3518-3526 (2015).

R.R. Patil, S. Turgman-Cohen, J. Šrogl, D. Kiserow, J. Genzer, "On-demand degrafting and the study of molecular weight and grafting density of poly(methyl methacrylate) brushes on flat silica substrates," Langmuir, 31, 2372-2381 (2015).

R.R. Patil, S. Turgman-Cohen, J. Šrogl, D. Kiserow, J. Genzer, "Direct measurement of molecular weight and grafting density by controlled and quantitative degrafting surface anchored poly(methyl methacrylate)," ACS Macro Letters, 5, 251-254 (2015).

R. Gurarslan, S.N. Hardrict, D. Roy, C. Galvin, M.R. Hill, H. Gracz, B.S. Sumerlin, J. Genzer, A E. Tonelli, "Beyond Microstructures: Using the Kerr Effect to Characterize the Macrostructures of Synthetic Polymers," J. Polymer Sci., Polymer Phys., 53, 155-166 (2015).

A.E. Özçam, R.J. Spontak, J. Genzer, "Toward the Development of a Versatile Functionalized Silicone Coating," ACS Applied Materials & Interfaces, 6, 22544-22552 (2014).

J. Allensworth, Y. Liu, H. Braun, J. Genzer, M.D. Dickey, "In-Plane Deformation of Shape Memory Polymer Sheets Programmed Using Only Scissors," Polymer, 50, 5948-5952 (2014).

S. Christau, T. Möller, Z. Yenice, J. Genzer, R. von Klitzing, "Brush/gold nanoparticle hybrids: Effect of grafting density on particle uptake and distribution within weak polyelectrolyte brushes," Langmuir, 30, 13033-13041 (2014).

X. Cai, J. Genzer, R.J. Spontak, "Evolution of Homopolymer Thin-Film Instability on Surface Anchored Diblock Copolymers Varying in Composition," Langmuir, 30, 11689-11695 (2014).

C.J. Galvin, M.D. Dimitriou, S.K. Satija, J. Genzer, "Swelling of Polyelectrolyte and Polyzwitterion Brushes by Humid Vapors," Journal of the American Chemical Society, 136, 12737-12745 (2014).

P.K. Schoch, J. Genzer, "Adsorption of ‘Soft’ Spherical Particles onto Sinusoidally-Corrugated Substrates," Soft Matter, 10, 7452-7458 (2014).

P.K. Schoch, J. Genzer, "Adsorption of Multiple Spherical Particles onto Sinusoidally-Corrugated Substrates," Langmuir, 30, 9407-9417 (2014).

Y. Liu, M. Miskiewicz, M.J. Escuti, J. Genzer, M.D. Dickey, "3-D Folding of Pre-Strained Polymer Sheets via Absorption of Laser Light," Journal of Applied Physics, 115, 204911 (2014).

G.J. Hayes, Y. Liu, J. Genzer, G. Lazzi, M.D. Dickey, "Self-Folding Origami Microstrip Antennas," IEEE Transactions on Antennas & Propagation, 62, 5416-5419 (2014).

A.E. Özçam, K. Efimenko, J. Genzer, "Effect of ultraviolet/ozone treatment on the surface and bulk properties of poly(dimethyl siloxane) and poly(vinylmethyl siloxane) networks," Polymer, 55, 3107-3119 (2014).

Y. Liu, R. Mailen, Y. Zhu, M.D. Dickey, J. Genzer, "Modeling Self-Folding Kinetics Using Thermal Shrinkage of Pre-Strained Polymer Sheets," Physical Review E, 89, 042601 (2014).

A. Kopyshev, C.J, Galvin, J. Genzer, N. Lomadze, S. Santer, "Opto-mechanical scission of polymer chains in photosensitive diblock-copolymer brushes," Langmuir, 29, 13967-13974 (2013).

R.L. Mays, M.D. Dickey, J. Genzer, "Microfluidic Channels Fabricated from Poly(vinylmethylsiloxane) Networks that Resist Swelling by Organic Solvents," Lab on Chip, 13, 4317-4320 (2013).

C. Salas, J. Genzer, L.A. Lucia, M.A. Hubbe, O.J. Rojas, "Water-wettable polypropylene fibers by facile surface treatment based on soy proteins," ACS Applied Materials & Interfaces, 5, 6541-6548 (2013).

M.D. Casper, A.O. Gözen, M.D. Dickey, J. Genzer, J.-P. Maria, "Surface wrinkling by chemical modification of poly(dimethylsiloxane)-based networks during sputtering," Soft Matter, 9, 7797–7803 (2013).

L.M. Johnson, L. Gao, C.W. Shields IV, M. Smith, K. Efimenko, K. Cushing, J. Genzer, G.P. López, "Elastomeric microparticles for acoustic mediated bioseparations," J. Nanobiotechology, 11, 22 (2013).

K.K. Goli, N. Gera, X. Liu, B.M. Rao, O.J. Rojas, J. Genzer, "Generation and properties of antibacterial coatings based on electrostatic attachment of silver nanoparticles to protein-coated polypropylene fibers," ACS Applied Materials & Interfaces, 5, 5298-5306 (2013).

R. Malik, C.K. Hall, J. Genzer, "Effect of Protein-like Copolymers Composition on the Phase Separation Dynamics of a Polymer Blend: A Monte Carlo Simulation," Macromolecules, 46, 4207-4214 (2013).

P. Datta, J, Genzer, "Computer Simulation of Template Polymerization using a Controlled Reaction Scheme." Macromolecules, 46, 2474-2484 (2013).

S.N. Hardrict, R. Gurarslan, C.J. Galvin, H. Gracz, D. Roy, B.S. Sumerlin, J. Genzer, A.E. Tonelli, "Characterizing Polymer Macrostructures by Identifying and Locating Microstructures Along Their Chains with the Kerr Effect," Journal of Polymer Science, Polymer Physics Edition, 51, 735-741 (2013

E.D. Bain, S. Turgman-Cohen, J. Genzer, "Computer simulation approaches for polymerization in grafted systems," Macromolecular Theory & Simulations, 22, 8-30 (2013).

K. Efimenko, A.E. Özçam, J. Genzer, D.A. Fischer, F.R. Phelan Jr., J.F. Douglas, "Self-Assembly Fronts in Collision: Impinging Ordering Organosilane Layers," Soft Matter, 9, 2493–2505 (2013).

C. Salas, O.J. Rojas, L.A. Lucia, M.A. Hubbe, J. Genzer, "On the surface interactions of proteins with lignin," ACS Applied Materials & Interfaces, 5, 199-206 (2013).

R.L. Mays, P. Pourhossein, D. Savithri, J. Genzer, R.C. Chiechi, M.D. Dickey, "Thiol-Containing Polymeric Embedding Materials for Nanoskiving," Journal of Materials Chemistry C, 1, 121-130 (2013).

Legend

Book chapters Book

K.K. Goli, O.J. Rojas, J. Genzer, "Formation and antifouling properties of amphiphilic coatings formed on polypropylene fibers," Biomacromolecules, 13, 3769-3779 (2012).

P. Datta, K. Efimenko, J. Genzer, "Effect of confinement on thermal frontal polymerization," Polymer Chemistry, 3, 3243-3246 (2012).

W. Powers, C.Y. Ryu, Y.K. Jhon, L.A. Strickland, C.K. Hall, J. Genzer, "Determining the Polydispersity in Chemical Composition and Monomer Sequence Distribution in Random Copolymers Prepared by Postpolymerization Modification of Homopolymers," ACS Macro Letters, 1, 1128-1133 (2012).

Q. Peng, K. Efimenko, J. Genzer, G.N. Parsons, "Oligomer Orientation in Vapor Molecular Layer Deposited Alkyl-Aromatic Polyamide Films," Langmuir, 28, 10464-10470 (2012).

J. Genzer, "Surface-Bound Gradients for Studies of Soft Materials Behavior," Annual Review of Materials Research, 42, 435-468 (2012).

G. Pandav, V. Pryamitsyn, K.C. Gallow, Y.-L. Loo, J. Genzer, V. Ganesan, "Applications of Surface-Grafted Macromolecules Derived from Post-Polymerization Modification Reactions," Soft Matter, 8, 6471-6482 (2012).

J. Genzer, P.G. Khalatur, A.R. Khokhlov, "Conformation-dependent design of synthetic functional copolymers," Comprehensive Polymer Science, Edited by M. Möller, K. Matyjaszewski, Elsevier, vol. 6, 689-723, 2012.

C.J. Galvin, J. Genzer, "Applications of Surface-Grafted Macromolecules Derived from Post-Polymerization Modification Reactions," Progress in Polymer Science, 13, 871-906 (2012).

J. Genzer, A.E. Özçam, J.A. Crowe-Willoughby, K. Efimenko, "Creating functional materials by chemical & physical functionalization of silicone elastomer networks," Silicone Surface Science, Edited by M. Owen, P. Dvornic, Springer, chapter 3, 59-94, 2012.

K.K. Goli, O.J. Rojas, A.E. Özçam, J. Genzer, "Generation of functional coatings on hydrophobic surfaces through deposition of denatured proteins followed by grafting from polymerization," Biomacrmolecules, 13, 1371-1382 (2012).

E.D. Bain, K. Dawes, A.E. Özçam, X. Hu, C.B. Gorman, J. Šrogl, J. Genzer, "Surface-Initiated Polymerization by Means of Novel, Stable, Non-Ester-Based Radical Initiator," Macrmolecules, 45, 3802-3815 (2012).

X. Liu, F. He, C. Salas, M. Pasquinelli, J. Genzer, O.J. Rojas, "Experimental and Computational Study of the Effect of Alcohols on the Solution and Adsorption Properties of a Nonionic Symmetric Triblock Copolymer," Journal of Physical Chemistry B, 116, 1289–1298 (2012).

C. Salas, O.J. Rojas, L.A. Lucia, M.A. Hubbe, J. Genzer, "Adsorption of glycinin and ß-conglycinin on silica and cellulose: surface interactions as a function of denaturation, pH, and electrolytes," Biomacromolecules, 13, 387-396 (2012).

A.O. Gozen, J. Genzer, R.J. Spontak, "Interfacial Stabilization of Bilayered Nanolaminates by Asymmetric Block Copolymers," Applied Physics Letters, 101, 101602 (2012).

S. Turgman-Cohen, J. Genzer, "Computer simulation of concurrent bulk- and surface-initiated living polymerization," Macromolecules, 45, 2128-2137 (2012).

A.E. Ozcam, K.E. Roskov, R.J. Spontak, J. Genzer, "Generation of Functional PET Microfibers through Surface-Initiated Polymerization," Journal of Materials Chemistry, 22, 5855-5864 (2012).

K. Gallow, Y.K. Jhon, J. Genzer, Y.-L. Loo, "Influence of Gradient Strength and Composition Profile on the Onset of the Cloud Point Transition in HEMA/DMAEMA Gradient Copolymers," Polymer, 53, 1131-1137 (2012).

J. Genzer, S. Arifuzzaman, R.R. Bhat, K. Efimenko, C.-l. Ren, I. Szleifer, "Time dependence of lysozyme adsorption on end-grafted polymer layers of variable grafting density and length," Langmuir, 28, 2122-2130 (2012).

A.E. Ozcam, K.E. Roskov, J. Genzer, R.J. Spontak, "Responsive PET Nano/Microfibers via Surface-Initiated Polymerization," ACS Applied Materials & Interfaces, 4, 59-64 (2012).

J.K. Gupta, K. Efimenko, D.A. Fischer, J. Genzer, N.L. Abbott, "Orientational Anchoring of Liquid Crystals on Surfaces Presenting Continuous Gradients in Composition," Soft Matter Gradient Surfaces: Methods and Applications, Edited by J. Genzer, John Wiley & Sons, New York, chapter 5, 109-128, 2012.

K. Efimenko, A.E. Özçam, J. Genzer, D.A. Fischer, F.R. Phelan, J.F. Douglas, "Colliding Self-Assembly Waves in Organosilane Monolayers," Soft Matter Gradient Surfaces: Methods and Applications, Edited by J. Genzer, John Wiley & Sons, New York, chapter 4, 93-107, 2012.

J. Genzer, R.R. Bhat, "Classification of key attributes of soft material gradients," Soft Matter Gradient Surfaces: Methods and Applications, Edited by J. Genzer, John Wiley & Sons, New York, chapter 2, 19-46, 2012.

Soft Matter Gradient Surfaces: Methods and Applications, Edited by J. Genzer, John Wiley & Sons, New York, 2012.

Y. Liu, J.K. Boyles, J. Genzer, M.D. Dickey, "Self-Folding of Polymer Sheets Using Local Light Absorption," Soft Matter, 8, 1764-1769 (2012).

Y.K. Jhon, S. Arifuzzaman, A.E. Ozçam, D. Kiserow, J. Genzer, "Formation of polyampholyte brushes via controlled radical polymerization and their assembly in solution," Langmuir, 28, 872-882 (2012).

R. Malik, C.K. Hall, J. Genzer, "Effect of Copolymer Compatibilizer Sequence on the Dynamics of Phase Separation of Immiscible Binary Homopolymer Blends," Soft Matter, 7, 10620-10630 (2011).

S. Turgman-Cohen, J. Genzer, "Simultaneous bulk- and surface-initiated controlled radical polymerization from planar substrates," Journal of the American Chemical Society, 133, 17567-17569 (2011).

R. Malik, C.K. Hall, J. Genzer, "Phase Separation Dynamics for a Polymer Blend Compatibilized by Protein-like Copolymers: A Monte Carlo Simulation," Macromolecules, 44, 8284-8293 (2011).

S. Volden, J. Genzer, K. Zhu, M.-H. G. Ese, B. Nystroem, W.R. Glomm, "Charge- and Temperature Dependent Interactions Between Anionic Poly(N-isopropylacrylamide) Polymers in Solution and a Cationic Surfactant at the Water/Air Interface," Soft Matter, 7, 8498-8507 (2011).

X. Liu, A.H. Vesterinen, J. Genzer, J.V. Seppaelae, O.J Rojas, "Adsorption of PEO-PPO-PEO Triblock Copolymers with End-Capped Cationic Chains of Poly (2-dimethylaminoethyl methacrylate)," Langmuir, 27, 9769-9780 (2011).

S. Voltrova, D. Hidasova, J. Genzer, J. Srogl, "Metallothionein-Inspired Prototype of Molecular Pincer," Chemical Communications, 47, 8067-8069 (2011).

S.M. Lane, Z. Kuang, J. Yom, S. Arifuzzaman, J. Genzer, B. Farmer, R. Naik, R.A. Vaia, "Poly(2-hydroxyethyl methacrylate) for enzyme immobilization - impact on activity and stability with Horseradish Peroxidase," Biomacromolecules, 12, 1822 (2011).

K. Gallow, Y.K. Jhon, W. Tang, J. Genzer, Y.-L. Loo, "Cloud Point Suppression in Dilute Solutions of Model Gradient Copolymers with Pre-specified Composition Profiles," Journal of Polymer Science, Polymer Physics B, 49, 629 (2011).

S. Ahmed, H.-K. Yang, A.E. Ozcam, K. Efimenko, M.C. Weiger, J. Genzer, J.M. Haugh, "Poly(vinylmethylsiloxane) Elastomer Networks as Functional Materials for Cell Adhesion and Migration Studies," Biomacromolecules, 12, 1265 (2011).

X. Liu, K.K. Goli, J. Genzer, O.J. Rojas, "Multilayers of Weak Polyelectrolytes of Low and High Molecular Mass Assembled on Polypropylene and Self-assembled Hydrophobic and Hydrophilic Surfaces," Langmuir, 27, 4541 (2011).

H.K. Yang, A.E. Ozcam, K. Efimenko, J. Genzer, "Photochromic materials with tunable color and mechanical flexibility," Soft Matter, 7, 3766 (2011).

A.O. Gozen, J. Zhou, K.E. Roskov, A.-C. Shi, J. Genzer, R.J. Spontak, "Block Copolymer Self-Organization vs. Interfacial Modification in Bilayered Thin-Film Laminates," Soft Matter, 7, 3268 (2011).

Y. Cho, W. Lee, Y.K. Jhon, J. Lim, J. Genzer, K. Char, "Polymer nanotubules obtained from the Layer-by-Layer Deposition within AAO Membrane Templates with Pore Diameters Less than 100 nm," Small, 6, 2683 (2010).

S. Turgman-Cohen, J. Genzer, "Computer simulation of controlled radical polymerization: Effect of chain confinement due to initiator grafting density and solvent quality in 'grafting from' method," Macromolecules, 43, 9567 (2010).

X. Liu, J. Song, D. Wu, J. Genzer, T. Theyson, O.J. Rojas, "Surface and friction behaviors of a silicone surfactant adsorbed on model nonwoven substrates," Industrial & Engineering Chemistry Research, 49, 8550 (2010).

A.E. Tonelli, Y.K. Jhon, J. Genzer, "The glass transition temperatures of styrene/p-BrS copolymers with variable co-monomer compositions and sequence distributions," Macromolecules, 43, 6912 (2010).

X. Liu, D. Wu, S. Turgman-Cohen, J. Genzer, T.W. Theyson, O.J. Rojas, "Adsorption of a nonionic symmetric tri-block copolymer on surfaces with different hydrophobicity," Langmuir, 26, 9565 (2010).

R. Malik, C.K. Hall, J. Genzer, "Protein-like Copolymers (PLCs) as Compatibilizers for Homopolymer Blends," Macromolecules, 43, 5149 (2010).

J.A. Crowe-Willoughby, D.R. Stevens, J. Genzer, L.I. Clarke, "Investigating the molecular origins of responsiveness in functional silicone elastomer networks," Macromolecules, 43, 5043 (2010).

L.A. Strickland, C.K. Hall, J. Genzer, "Simulation of mechanically-assembled monolayers in poor solvent using discontinuous molecular dynamics," Macromolecules, 43, 3072 (2010).

L.A. Strickland, C.K. Hall, J. Genzer, "Controlling co-monomer distribution in random copolymers by chemical coloring of surface-tethered homopolymers: An insight from discontinuous molecular dynamics simulation," Langmuir, 26, 8810 (2010).

M.B. Smith, D.J. McGillivray, J. Genzer, M. Losche, P.K. Kilpatrick, "Neutron reflectometry of supported hybrid bilayers with inserted peptide," Soft Matter, 6, 682 (2010).

S. Volden, A.-L. Kjoniksen, K. Zhu, J. Genzer, B. Nystrom, W.R. Glomm, "Temperature-dependent optical properties of gold nanoparticles coated with a charged diblock copolymer and an uncharged triblock copolymer," ACS Nano, 4, 1187 (2010).

E. Cadova, J. Konecny, J. Kris, R. Svitakova, P. Holler, J. Genzer, P. Vlcek, "ATRP of 2-vinyl pyridine and tert-butyl acrylate mixtures giving precursors of polyampholytes," Journal of Polymer Science A, Polymer Chemistry, 48, 735 (2010).

J.A. Crowe-Willoughby, K.L. Weiger, A.E. Ozcam, J. Genzer, "Formation of silicone elastomer networks films with gradients in modulus," Polymer, 51, 763 (2010).

M. Cohen Stuart, W. Huck, J. Genzer, M. Mueller, C.K. Ober, M. Stamm, G. Sukhorukov, I. Szleifer, V. Tsuktruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, S. Minko, "Stimuli-responsive polymer materials for sensors, actuators, coatings, and delivery systems," Nature Materials, 9, 101 (2010).

2009-2000

L.A. Strickland, C.K. Hall, J. Genzer, "Design of copolymers with tunable randomness using discontinuous molecular dynamics simulation," Macromolecules, 42, 9063 (2009).

J. Kim, G. Montero, Y. Habibi, J.P. Hinestroza, J. Genzer, D.S. Argyropoulos, O.J. Rojas, "Dispersion of Cellulose Crystallites by Nonionic Surfactants in Hydrophobic Composites," Polymer Engineering and Science, 49, 2054 (2009).

J. Han, B.H. Jeon, C.Y. Ryu, J.J. Semler, Y.K. Jhon, J. Genzer, "Discriminating Among Co-monomer Sequence Distributions in Random Copolymers Using Interaction Chromatography," Macromolecular Rapid Communications, 30, 1543 (2009).

A.E. Ozcam, K. Efimenko, C. Jaye, R.J. Spontak, D.A. Fischer, J. Genzer, "Modification of PET surfaces with self-assembled monolayers of organosilane precursors," Journal of Electron Spectroscopy and Related Phenomena, 172, 95 (2009).

S. Turgman-Cohen, D.A. Fischer, P.K. Kilpatrick, J. Genzer, "Asphaltene adsorption onto self-assembled monolayers of alkyltrichlorosilanes of varying chain length," ACS Applied Materials and Interfaces, 1, 1347 (2009).

S. Turgman-Cohen, M.B. Smith, D.A. Fischer, P.K. Kilpatrick, J. Genzer, "Asphaltene adsorption onto self-assembled monolayers of mixed aromatic and aliphatic trichlorosilanes," Langmuir, 25, 6260 (2009).

K.E. Sohn, M.D. Dimitriou, J. Genzer, D.A. Fischer, C.J. Hawker, E.J. Kramer, "Depth Profiling the Near Surface of Polymer Films Using NEXAFS Spectroscopy," Langmuir, 25, 6341 (2009).

S. Arifuzzaman, A.E. Ozcam, K. Efimenko, D.A. Fischer, J. Genzer, "Formation of surface-grafted polymeric amphiphilic coatings comprising ethylene glycol and fluorinated groups and their response to protein adsorption," Biointerphases, 4, FA33 (2009).

K. Efimenko, J. Finlay, M.E. Callow, J.A. Callow, J. Genzer, "Development and testing of hierarchically wrinkled coatings for marine antifouling," ACS Applied Materials and Interfaces, 1, 1031 (2009).

S. Diamanti, S. Arifuzzaman, J. Genzer, R.A. Vaia, "Tuning gold nanoparticle - poly(2-hydroxyethyl methacrylate) brush interactions: From reversible swelling to capture and release," ACS Nano, 3, 807 (2009).

Y.K. Jhon, J.J. Semler, J. Genzer, M. Beevers, O. Gus'kova, P.G. Khalatur, A.R. Khokhlov, "Effect of co-monomer sequence distribution on the adsorption of random copolymers onto impenetrable flat surfaces," Macromolecules, 42, 2843 (2009).

I. Park, K. Efimenko, J. Sjoblom, J. Genzer, "Rapid removal of organics and oil spills from waters using silicone rubber "sponges," Journal of Dispersion Science and Technology, 30, 318 (2009).

J.A. Crowe-Willoughby, J. Genzer, "Formation and properties of responsive siloxane-based polymeric surfaces with tunable surface reconstruction kinetics," Advanced Functinoal Materials, 19, 460 (2009).

E. Sivaniah, J. Genzer, A. Hexemer, E.J. Kramer, M.L. Xiang, X.F. Li, C.K. Ober, S. Magonov, "Non-planar surface organization of dendrons in side-chain modified liquid crystalline block copolymers," Macromolecules, 41, 9940 (2008).

M.R. Tomlinson, J. Genzer, "Formation and properties of multivariant assemblies of surface-tethered diblock and triblock copolymers," Polymer, 49, 4837 (2008).

Y.K. Jhon, J.J. Semler, J. Genzer, "Effect of solvent quality and chain confinement on the kinetics of polystyrene bromination," Macromolecules, 41, 6719 (2008).

B. Wei, P.A. Gurr, A.O. Gozen, A. Blencowe, D.H. Solomon, G.G. Qiao, R.J. Spontak, J. Genzer, "Autophobicity-Driven Surface Segregation and Patterning of Core-Shell Microgel Particles," Nano Letters, 8, 3010 (2008).

L.A. Strickland, C.K. Hall, J. Genzer, "Simulation of Mechanically-Assembled Monolayers and Polymers In Good Solvent Using Discontinuous Molecular Dynamics," Macromolecules, 41, 6573 (2008).

S. Diamanti, S. Arifuzzaman, A. Elsen, J. Genzer, R.A. Vaia, "Reactive Patterning via Post-Functionalization of Polymer Brushes Utilizing Disuccinimidyl Carbonate Activation to Couple Primary Amines," Polymer, 49, 3770 (2008).

J. Genzer, A. Marmur, "Biological and man-made self cleaning surfaces," MRS Bulletin, 33, 742-746 (2008).

.B. Gorman, R.J. Petrie, J. Genzer, "Effect of Substrate Geometry on Polymer Molecular Weight and Polydispersity during Surface-Initiated Polymerization," Macromolecules, 41, 4856-4865 (2008).

J. Genzer, R.R. Bhat, "Surface-bound soft matter gradients," Langmuir, 24, 2294 (2008).

J. Guo, P. Resnick, K. Efimenko, J. Genzer, J.M. DeSimone, "Alternative Fluoropolymers to Avoid the Challenges Associated With Perfluorooctanoic Acid," Ind. Eng. Chem. Res., 47, 502 (2008).

P. Ritz, P. Latalova, J. Kriz, J. Genzer, P. Vlcek, "Statistical copolymers of 2-(trimethylsilyoxy)ethyl methacrylate and methyl methacrylate synthesized by ATRP," Journal of Polymer Science, Polymer Chemistry, 46, 1919 (2008).

C.L. Rhodes, S. Lappi, D. Fischer, S. Sambasivan, J. Genzer, S. Franzen, "Characterization of Monolayer Formation on Aluminum-doped Zinc Oxide Thin Films," Langmuir, 24, 433 (2008).

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Book chapters

J.A. Crowe, K. Efimenko, J. Genzer, "Manipulating Siloxane Surfaces: Obtaining the Desired Surface Function via Engineering Design," The Science and Technology of Silicones and Silicone-Modified Materials, Edited by S. Clarson, ACS Proceedings, 222-255, 2007.

P. Ritz, P. Latalova, M. Janata, L. Toman, J. Kriz, J. Genzer, P. Vlcek, "Synthesis of amphiphlic copolymers by ATRP initiated with a bifunctional initiator having trichloromethyl groups," Reactive Functional Polymers, 67, 1027 (2007).

P. Gong, T. Wu, J. Genzer, and I. Szleifer, "Behavior of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates: 2. Theory," Macromolecules, 40, 8765 (2007).

T. Wu, P. Gong, I. Szleifer, P. Vlcek, V. Subr, and J. Genzer, "Behavior of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates: 1. Experiment," Macromolecules, 40, 8756 (2007).

A. Jayaraman, C.K. Hall, J. Genzer, "Computer simulation study of probe-target hybridization in model DNA microarrays: Effect of probe surface density and target concentration," Journal of Chemical Physics, 127, 144912 (2007).

J.J. Semler, Y.K. Jhon, A. Tonelli, M. Beevers, R. Krishnamoorti, J. Genzer, "Facile method of controlling monomer sequence distributions in random copolymers," Advanced Materials, 19, 2877 (2007).

A. Jayaraman, E.E. Santiso, C.K. Hall, J. Genzer, "Theoretical study of kinetics of zipping phenomena in biomimetic polymers," Physical Review E, 76, 011715 (2007).

M. Cerruti, C. Rhodes, M. Losego, A. Efremenko, J. Genzer, J.P. Maria, D.A. Fischer, D. Feldheim, S. Franzen, "Influence of Indium-Tin Oxide surface structure on the ordering and coverage of organosilane, carboxylic acid and thiol monolayers," Journal of Physics D: Applied Physics, 40, 4212 (2007).

J.F. Douglas, K. Efimenko, D.A. Fischer, F.R. Phelan, J. Genzer, "Propagating Waves of Self-Assembly in Organosilane Monolayers," Proc. Nat. Acad. Sci. USA, 104, 10324 (2007).

A.J. Schultz, C.K. Hall, J. Genzer, "Obtaining concentration profiles from computer simulation structure factors," Macromolecules, 40, 2629 (2007).

J. Kim, K. Efimenko, J. Genzer, R.G. Carbonell, "Deposition of Poly[2-(perfluorooctyl)ethyl acrylate] from Liquid CO2 High Pressure Free Meniscus Coating. Part 2: Surface Properties," Macromolecules, 40, 588 (2007).

M.B Smith, K. Efimenko, D.A. Fischer, S.E. Lappi, P.K. Kilpatrick, J. Genzer, "Study of the Packing Density and Molecular Orientation of Bimolecular Self-Assembled Monolayers of Aromatic and Aliphatic Organosilanes on Silica," Langmuir, 23, 673 (2007).

P. Gong, J. Genzer, I. Szleifer, "Phase Behavior and Charge Regulation ofWeak Polyelectrolyte Grafted Layers," Physical Review Letters, 98, 018203 (2007).

R.R. Bhat, J. Genzer, "Tuning the number density of nanoparticles by multivariant tailoring of attachment points on flat substrates," Nanotechnology, 18, 025301 (2007).

J. Genzer, K. Efimenko, "Recent developments in superhydrophobic surfaces and their relevance to marine fouling: a review," Biofouling, 22, 339 (2006)

J. Genzer, "In silico polymerization: Computer simulation of controlled radical polymerization in bulk and on flat surfaces," Macromolecules, 39, 7157 (2006).

B. Wei, P.G. Lam, M.B. Braunfeld, D.A. Agard, J. Genzer, R.J. Spontak, "Tunable Instability Mechanisms of Polymer Thin Films by Molecular Self-Assembly," Langmuir, 22, 8642 (2006).

J. Genzer, K. Efimenko, D.A. Fischer, "Formation mechanisms and properties of semifluorinated molecular gradients on silica surfaces," Langmuir, 22, 8532 (2006).

A. Jayaraman, C.K. Hall, J. Genzer, "Computer Simulation Study of Molecular Recognition in Model DNA Microarrays," Biophysical Journal, 91, 2227 (2006).

J.J. Semler, J. Genzer, "Design of Random Copolymers with Statistically Controlled Monomer Sequence Distributions via Monte Carlo Simulations," Journal of Chemical Physics, 125, 014902 (2006).

B. H. Clare, K. Efimenko, D.A. Fischer, J. Genzer, N.L. Abbott, "Orientations of Liquid Crystals in Contact with Surfaces that Present Continuous Gradients of Chemical Functionality," Chemistry of Materials, 18, 2357 (2006).

Y.K. Jhon, R.R. Bhat, C. Jeong, O.J. Rojas, I. Szleifer, J. Genzer, "Salt-induced depression of lower critical solution temperature in surface-grafted neutral thermoresponsive polymer," Macromolecular Rapid Communications, 27, 697 (2006).

J. Genzer, J. Groenewold, "Soft matter with hard skin: From skin wrinkles to templating and material characterization," Soft Matter, 2, 310 (2006).

M.B. Smith, J. Tong, J. Genzer, D.A. Fischer, P.K. Kilpatrick, "Ionic Solution Conductance Through Oriented Peptide Channels in Supported Hybrid Bilayers," Langmuir, 22, 1919 (2006).

R.R. Bhat, M.R. Tomlinson, T. Wu, J. Genzer, "Surface-Grafted Polymer Gradients: Formation, Characterization and Applications," Advances in Polymer Science, 198, 51 (2006).

Legend

Contributed publications

R.R. Bhat, J. Genzer, "Combinatorial Study of Nanoparticle Dispersion in Surface-Grafted Macromolecular Gradients," Applied Surface Science, 252, 2549 (2005).

R.R. Bhat, B.N. Chaney, J. Rowley, A. Liebmann-Vinson, J. Genzer, "Controlling Cell Adhesion Using Surface-Grafted Polymer Gradient Assemblies," Advanced Materials, 17, 2802 (2005).

J.A. Crowe, J. Genzer, "Creating Responsive Surfaces with Tailored Wettability Switching Kinetics and Reconstruction Reversibility," Journal of the American Chemical Society, 127, 17610 (2005).

M.R. Tomlinson, R.R. Bhat, J. Genzer, "Orthogonal Polymer Brush Gradients: Formation and Applications," Polymer Preprints, 46(2), 44 (2005).

E. Manias, M. Rackaitis, T.M.D. Foley, K. Efimenko, J. Genzer, "Combinatorial Polymer Brushes Formed by Temperature-Responsive Polymers with Tunable Onset of Response," E. Manias, M. Rackaitis, T.M.D. Foley, K. Efimenko, J. Genzer, Polymer Preprints, 46(2), 11 (2005).

M.R. Tomlinson, J. Genzer, "Evolution of Surface Morphologies in Multivariant Assemblies of Surface-Tethered Diblock Copolymers after Selective Solvent Treatment," Langmuir, 21, 11552 (2005).

V. Carla, K. Wang, Y. Hussain, K. Efimenko, J. Genzer, C.S. Grant, G.C. Sarti, R.G. Carbonell, F. Doghieri, "Non-Equilibrium Model for Sorption and Swelling of Bulk Glassy Polymer Films with Supercritical Carbon Dioxide," Macromolecules, 38, 10299 (2005).

R.R. Bhat, J. Genzer, "Using spectroscopic ellipsometry for quick prediction of number density of nanoparticles bound to non-transparent solid surfaces," Surface Science, 596, 187 (2005).

R.R. Bhat, M.R. Tomlinson, J. Genzer, "Orthogonal Surface-Grafted Polymer Gradients: A Versatile Combinatorial Platform," Journal of Polymer Science, Polymer Physics Edition, 43, 3384 (2005).

A. Jayaraman, C.K. Hall, J. Genzer, "Computer simulation study of pattern transfer in AB diblock copolymer adsorbed on a heterogeneous surface," Journal of Chemical Physics, 123, 124702 (2005).

K. Efimenko, J.A. Crowe, E. Manias, D.W. Schwark, D.A. Fischer, and J. Genzer, "Rapid formation of soft hydrophilic silicone elastomer surfaces," Polymer, 46, 9329 (2005).

J. Seog, D. Dean, B. Rolauffs, T. Wu, J. Genzer, A. H.K. Plaas, A. J. Grodzinsky, C. Ortiz, "Nanomechanics of opposing glycosaminoglycan macromolecules," Journal of Biomechanics, 38, 1789 (2005).

A. Striolo, A. Jayaraman, J. Genzer, C.K. Hall, "Adsorption of Comb Copolymers on Weakly-Attractive Solid Surfaces," Journal of Chemical Physics, 123, 064710 (2005).

J. Genzer, "Templating surfaces with gradient assemblies," Journal of Adhesion, 81, 417 (2005).

K. Efimenko, M. Rackaitis, E. Manias, A. Vaziri, L. Mahadevan, J. Genzer, "Nested self-similar wrinkling patterns in skins," Nature Materials, 4, 293 (2005).

A.J. Schultz, C.K. Hall, J. Genzer, "Computer Simulation of Block Copolymer/Nanoparticle Composites," Macromolecules, 38, 3007 (2005).

A. Jayaraman, C.K. Hall, J. Genzer, "Designing pattern recognition surfaces for selective adsorption of copolymer sequences using lattice Monte Carlo simulation," Physical Review Letters, 94, 078103 (2005).

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Book chapters

R.J. Petrie, T.N. Bailey, C.B. Gorman, J. Genzer, "Fast directed motion of "fakir" drops," Langmuir, 20, 9893 (2004).

B. Wei, P.A. Gurr, J. Genzer, G.G. Qiao, D.H. Solomon, R.J. Spontak, "Dewetting of star nanogel/homopolymer blends from an immiscible homopolymer substrate," Macromolecules, 37, 7857 (2004).

B. Wei, J. Genzer, R.J. Spontak, "Dewetting behavior of a block copolymer/homopolymer thin film on an immiscible homopolymer substrate," Langmuir, 20, 8659 (2004).

L. Fleming, M.D. Ulrich, K. Efimenko, J. Genzer, A.S.Y. Chan, T.E. Madey, S.-J. Oh, O. Zhou, J.E. Rowe, "NEXAFS and UPS studies of aligned single-walled carbon nanotubes on Si(100) substrates," J. Vac. Sci. Technol. B, 22, 2000 (2004).

T. Wu, J. Genzer, P. Gong, I. Szleifer, P. Vlcek, V. Šubr, "Behavior of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates," Polymer Brushes, Edited by B. Brittain, R. Advincula, J. Rühe, and K. Caster, John Wiley & Sons, Chapter 15, 2004.

J.J. Semler, J. Genzer, "Monte Carlo simulations of copolymer adsorption at planar chemically patterned surfaces: Effect of interfacial interactions," Macromol. Theory. Simul., 13, 219 (2004).

R.R. Bhat, J. Genzer, "Development of high-throughput substrates for generating two-dimensional nanoparticles assemblies and for screening protein adsorption," Mat. Res. Soc. Symp. Proc., 804, JJ.5.8.1 (2004).

A.J. Schultz, C.K. Hall, J. Genzer, "Box length search algorithm for molecular simulation of systems containing periodic structures," J. Chem. Phys., 120, 2049 (2004).

R.R. Bhat, M.R. Tomlinson, J. Genzer, "Assembly of nano-sized objects using surface-grafted orthogonal polymer gradients," Macromolecular Rapid Communications, 25, 270 (2004).

D.A. Fischer, K. Efimenko, R.R. Bhat, S. Sambasivan, J. Genzer, "Mapping surface chemistry and molecular orientation with combinatorial near edge X-ray absorption fine structure," Macromolecular Rapid Communications, 25, 141 (2004).

Legend

Book chapters Contributed publications

W. Wu, S. Sambasivan, C.Y. Wang, W.E. Wallace, J. Genzer, D.A. Fischer, "A Direct Comparison of Surface and Bulk Chain Relaxation in Polystyrene," European Physical Journal E, 12, 127 (2003).

T. Wu, M. Tomlinson, K. Efimenko, J. Genzer, "A combinatorial approach to surface anchored polymers," Journal of Materials Science, 38, 4471 (2003).

J. Genzer, K. Efimenko, D.A. Fischer, "Fabricating two-dimensional molecular gradients via asymmetric deformation of uniformly-coated elastomer sheets," Advanced Materials, 15, 1545 (2003).

R.R. Bhat, J. Genzer, B.N. Chaney, H.W. Sugg, A. Liebmann-Vinson, "Controlling the assembly of nanoparticles using molecular and macromolecular gradients," Nanotechnology, 14, 1145 (2003).Nanotechnology, 14, 1145 (2003).

J.J. Semler, J. Genzer, "Monte Carlo Simulations of Copolymer Adsorption at Planar Chemically Patterned Surfaces: Effect of Surface Domain Sizes," Journal of Chemical Physics, 119, 5274 (2003).

M.R. Tomlinson, J. Genzer, "Formation of surface-grafted diblock copolymer brushes with continuous composition gradients," Chemical Communications, No. 12, 1350 (2003).

M.R. Tomlinson, J. Genzer, "Formation of grafted macromolecular assemblies with a gradual variation of molecular weight on solid substrates," Macromolecules, 36, 3449 (2003).

T. Wu, K. Efimenko, P. Vlcek, V. Šubr, J. Genzer, "Formation and properties of anchored polymers with a gradual variation of grafting densities on flat substrates," Macromolecules, 36, 2448 (2003).

M.R. Tomlinson, T. Wu, K. Efimenko, J. Genzer, "Gradient polymer brushes: Preparation and applications," Polymer Preprints, 44(1), 468 (2003).

J. Genzer, R. Bhat, T. Wu, K. Efimenko, "Molecular Gradient Nanoassemblies," Encyclopedia of Nanoscience & Nanotechnology, (H. S. Nalwa, Ed.), American Scientific Publishers, VOl. 5, pp. 663-676, 2003.

J. Genzer, D. A. Fischer, K. Efimenko, "Combinatorial near-edge x-ray absorption fine structure: Simultaneous determination of molecular orientation and bond concentration on chemically heterogeneous surfaces," Appl. Phys. Lett., 82, 266 (2003).

Legend

Book chapters

J. Genzer, E. J. Kramer, D. A. Fischer, "Application of near-edge absorption fine structure (NEXAFS) to studies of surface molecular orientation of model organic molecules," J. Appl. Phys., 92, 7070 (2002).

A. J. Schultz, C. K. Hall, J. Genzer, "Computer simulation of copolymer phase behavior," J. Chem. Phys., 117, 10329 (2002).

J. Genzer, K. Efimenko, D. A. Fischer, "Molecular orientation and grafting density in semifluorinated self-assembled monolayers of mono-, di- and trichloro silanes on silica substrates," Langmuir, 18, 9307 (2002).

K. Efimenko, W. E. Wallace, J. Genzer, "Surface modification of Sylgard-184 poly(dimethyl siloxane) networks by ultraviolet and ultraviolet/ozone treatment," J. Colloid Interface Sci., 254, 306 (2002).

K. Efimenko, J. Genzer, "Tuning the surface properties of elastomers using hydrocarbon-based mechanically assembled monolayers," Mat. Res. Soc. Symp. Proc., 705, DD10.3.1-DD10.3.6 (2002).

J. Semler, J. Genzer, "Monte Carlo Simulations of Copolymer Adsorption from Copolymer / Homopolymer Melts at Planar Chemically Patterned Surfaces," Mat. Res. Soc. Symp. Proc., 710, DD8.5.1-DD8.5.6 (2002).

J. Genzer, T. Wu, K. Efimenko, "Planar Molecular and Macromolecular Gradients: Preparation and Properties," Mat. Res. Soc. Symp. Proc., 710, Y8.8.1-Y8.8.6 (2002).

T. Wu, K. Efimenko, J. Genzer, "Multivariant investigation of the mushroom-to-brush transition in surface-anchored poly(acrylamide)," J. Am. Chem. Soc., 124, 9394-9395 (2002).

J. Genzer, "Molecular gradients: Formation and applications in soft condensed matter science," Encyclopedia of Materials Science, K.H. J. Buschow, R. W. Cahn, M. C. Flemings, B. Ilschner, E. J. Kramer, S. Mahajan, Eds.), Elsevier, 2002.

K. Efimenko, B. Novick, R. G. Carbonell, J. M. DeSimone, J. Genzer, "Formation of self-assembled monolayers of from semifluorinated and hydrocarbon chlorosilane precursors on silica surfaces: A comparison of various deposition techniques," Langmuir, 18, 6170-6179 (2002).

R. R. Bhat, D. A. Fischer, J. Genzer, "Fabricating planar nanoparticle assemblies with number density gradients," Langmuir, 18, 5640-5643 (2002).

J. Genzer, "Copolymer adsorption on planar chemically heterogeneous substrates: The interplay between the monomer sequence distribution and interaction energies," Macromol. Theory. Simul., 11, 481-493 (2002).

R. J. Composto, R. M. Walters, J. Genzer, "Application of ion scattering techniques to characterize polymer surfaces and interfaces," Mat. Sci. Eng. R, 38, 107-180 (2002).

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Contributed Publications

J. Martinache, J. R. Royer, S. Sirpurapu, F. E. Hénon, J. Genzer, S. A. Khan, R. G. Carbonell, "Processing of polyamide 11 with supercritical carbon dioxide," Ind. Eng. Chem. Res., 40 5570-5577 (2001).

J. Genzer, "Copolymer adsorption on planar substrates with a random distribution of chemical heterogeneities," J. Chem. Phys., 115 4873-4882 (2001).

J. Genzer, K. Efimenko, "Synchrotron studies of oligomer and polymer assemblies on elastomeric surfaces," NSLS Newsletter, 12-14, November 2001.

K. Efimenko, J. Genzer, "How to prepare tunable planar molecular chemical gradients," Adv. Mater., 13, 1560-1563 (2001).

W. E. Wallace, D. A. Fischer, K. Efimenko, W. Wu, J. Genzer, "Polymer chain relaxation: Surface outpaces bulk," Macromolecules, 34, 5081-5082 (2001).

E. Sivaniah, J. Genzer, G. H. Fredrickson, E. J. Kramer, M. Xiang, X. Li, C. K. Ober, S. Magonov, "Periodic surface topology of 3-arm semifluorinated alkane monodendron diblock copolymers," Langmuir, 17, 4342-4346 (2001).

J. Genzer, "Self-Consistent Field Study of Copolymer Adsorption at Planar Chemically ‘Rough’ Surfaces: An Interplay Between The Substrate Chemical Pattern and Copolymer Sequence Distribution," Adv. Colloid Interface Sci., 94, 105-134 (2001).

T. Wu, K. Efimenko, J. Genzer, "Preparing High-Density Polymer Brushes by Mechanically Assisted Polymer Assembly (MAPA)," Macromolecules, 34, 684-686 (2001).

J. Genzer, "Copolymer assisted generation of 3D pattern by replicating 2D substrate motifs," Phys. Rev. E, 63, 022601-1 -022601-4 (2001).

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Contributed Publications

W. E. Wallace, K. Efimenko, W. Wu and J. Genzer, "Polymer chain relaxation: Surface outpaces bulk," NSLS Activity Report - Science Highlights, 2-11 - 2-12, (2000).

J. Genzer, K. Efimenko, "Tuning the Surfaces of Elastomers Through Mechanically Assembled Monolayers," NSLS Activity Report - Science Highlights, 2-68 - 2-71, (2000).

J. Genzer, K. Efimenko, "Creating long-lived superhydrophobic polymer surfaces through mechanically assembled monolayers," Science, 290, 2130-2133 (2000).

T. Hyakawa, J. Wang, M. Xiang, X. Li, M. Ueda, C. K. Ober, J. Genzer, E. Sivaniah, E. J. Kramer, D. A. Fischer, "The effect of changing molecular end groups on surface properties: Synthesis and characterization of poly(styrene-b-semifluorinated isoprene) block copolymers with -CF2H end groups," Macromolecules, 33, 8012-8019 (2000).

E. Manias, H. Chen, R. Krishnamoorti, J. Genzer, E. J. Kramer, E. P. Giannelis, "The mobility of long polymers in nanometer confinements," Macromolecules, 33, 7955-7966 (2000).

A. Michel, R. M. Felder, J. Genzer, R. Fuller, "Student use of instructional technology in the introductory chemical engineering course," Proceedings of the 2000 ASEE Annual Meeting, June 2000.

M. Xiang, X. Li, C. K. Ober, K. Char, J. Genzer, E. Sivaniah, E. J. Kramer, D. A. Fischer, "Surface stability in liquid-crystalline block copolymers with semifluorinated side groups," Macromolecules, 33, 6106-6119 (2000).

J. Genzer, E. Sivaniah, E. J. Kramer, J. Wang, M. Xiang, K. Char, C. K. Ober, R. A. Bubeck, D. A. Fischer, M. Graupe, R. Colorado, Jr., O. E. Shmakova, T. R. Lee, "Molecular orientation of single and 2-armed monodendron semifluorinated chains on “soft” and “hard” surfaces studied using NEXAFS," Macromolecules, 33, 6068-6077 (2000).

J. Genzer, E. Sivaniah, E. J. Kramer, J. Wang, H. Körner, M. Xiang, K. Char, C. K. Ober, B. M. DeKoven, R. A. Bubeck, M. K. Chaudhury, S. Sambasivan, D. A. Fischer, "The orientation of semifluorinated alkanes attached to polymers at the surface of polymer films," Macromolecules, 33, 1882-1887 (2000).

J. Genzer, E. Sivaniah, E. J. Kramer, J. Wang, H. Körner, K. Char, C. K. Ober, B. M. DeKoven, R. A. Bubeck, D. A. Fischer, S. Sambasivan, "Temperature dependence of molecular orientation on the surfaces of semifluorinated polymer thin films," Langmuir, 16, 1993-1997 (2000).

1999-1990

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Contributed Publications

K. Ober, M. L. Xiang, K. Char K, J. Genzer, E. Sivaniah, E. J. Kramer, D. Fisher, "Block copolymers with low surface energy, liquid crystalline segments: The interplay of surface and bulk liquid crystallinity," Polym. Prep., 40, 976-977 (1999).

C. K. Ober, M. L. Xiang, K. Char K, J. Genzer, E. Sivaniah, E. J. Kramer, D. Fisher, "Low surface energy materials: Liquid-crystalline polymers with semifluorinated monodendron side groups," Abstr. Pap. Am. Chem. Soc., 217 (2), 159-160 (1999).

J. Heier, J. Genzer, E. J. Kramer, F. S. Bates, S. Walheim, G. Krausch, "Transfer of a chemical substrate pattern into an island-forming diblock copolymer film," J. Chem. Phys., 111, 11101-11110 (1999).

J. Genzer, J. Heier, E. J. Kramer, "Wetting reversal transition in phase-separated polymer mixtures," Macromol. Symp., 139, 77-87 (1999).

R. Oslanec, J. Genzer, A. Faldi, R. J. Composto, P. D. Garrett, "Surface enrichment in a miscible random copolymer blend: Influence of polydispersity and architecture," Macromolecules, 32, 4098-4105 (1999).

J. Genzer, R. J. Composto, "The interface between immiscible polymers studied by low-energy forward recoil spectrometry and neutron reflectivity," Polymer, 40, 4223-4228 (1999).

J. Genzer, E. J. Kramer, "Pretransitional thinning of a polymer wetting layer," Europhys. Lett., 44, 180-185 (1998).

J. Genzer, E. Sivaniah, E. J. Kramer, J. Wang, H. Körner, M. Xiang, S. Yang, C. K. Ober, K. Char, M. K. Chaudhury, B. M. DeKoven, R. A. Bubeck, D. A. Fischer, S. Sambasivan, "Surfaces of semifluorinated block copolymers studied using NEXAFS," Mat. Res. Soc. Symp. Proc., 524, 365-370 (1998).

J. Genzer, R. J. Composto, "The effect of molecular weight on the interfacial excess, tension, and width in a homopolymer/binary polymer blend system," Macromolecules, 31, 870-878 (1998).

J. Genzer, E. J. Kramer, "Wetting reversal transition in phase-separated polymer mixtures," Phys. Rev. Lett., 78, 4946-4949 (1997).

J. Genzer, R. J. Composto, "Surface segregation amplification in miscible polymer blends near criticality," Europhys. Lett., 38, 171-176 (1997).

J. Genzer, R. J. Composto, "A self-consistent field study of the wetting transition in binary polymer blends," J. Chem. Phys., 106, 1257-1263 (1997).

J. Genzer, A. Faldi, R. J. Composto, "Mean-field theory of the interface between a homopolymer and a binary-polymer mixture," J. Chem. Phys., 105, 10134-10144 (1996).

J. Genzer, A. Faldi, R. Oslanec, R. J. Composto, "Surface enrichment in a miscible polymer blend: An experimental test of self-consistent field and long-wavelength approximation models," Macromolecules, 29, 5438-5445 (1996).

A. Faldi, J. Genzer, R. J. Composto, W. D. Dozier, "Segregation at the Interface between a Homopolymer and a Binary Polymer Blend," Phys. Rev. Lett., 74, 3388-3391 (1995).

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Contributed Publications

A. Faldi, J. Genzer, R. J. Composto, W. D. Dozier, "Segregation at the polymer/binary polymer blend interface," Abstr. Pap. Am. Chem. Soc., 208 (2), 156- (1994).

J. Genzer, A. Faldi, R. J. Composto, "Self-consistent mean field calculation of surface segregation in a binary polymer blend," Phys. Rev. E, B50, 2373-2376 (1994).

J. Genzer, J. B. Rothman, R. J. Composto, "Improved hydrogen and deuterium depth profiling in polymers using low energy forward recoil spectrometry," Nucl. Instr. Meth. Phys. Res., B86, 345- (1994).

W. E. Wallace, Q. Zhong, J. Genzer, R. J. Composto, D. A. Bonnell, "On the use of ion scattering to examine the role of hydrogen reduction of TiO2," J. Mat. Res., 8, 1629- (1993).

J. Genzer, P. Machac, V. Myslik, "Modified four-point method of contact resistance measurement," Slaboproudy Obzor (Czech), 52, 130- (1991).

J. Genzer, V. Svorcik, V. Rybka, "Survey of the reactions of some metals with GaAs applicable in semiconductor technique," Chemicke Listy (Czech), 84, 1146- (1990).

1989

V. Rybka, V. Myslik, V. Svorcik, J. Genzer, L. Hudec, "Description of a technological laser usable for preparation of ohmic contacts to n-GaAs by graded gap heterojunction method," Chemicke Listy (Czech), 84, 1146- (1990).